Nanoarchitectonics of Metal-Organic Frameworks for Capacitive Deionization via Controlled Pyrolyzed Approaches

Next-generation desalination technologies are needed to meet the increasing demand for clean water. Capacitive deionization (CDI) is a thermodynamically efficient technique to treat non-potable water with relatively low salinity. The salt removal capacity and rate of CDI are highly dependent on the electrode materials, which are preferentially porous to store ions through electrosorption and/or redox reactions. Metal-organic frameworks (MOFs) with "infinite" combinations of transition metals and organic linkers simplify the production of carbonaceous materials often with redox-active components after pyrolysis. MOFs-derived materials show great tunability in both compositions and structures but require further refinement to improve CDI performance. This review article summarizes recent progress in derivatives of MOFs and MOF-like materials used as CDI electrodes, focusing on the structural and compositional material considerations as well as the processing parameters and electrode architectures of the device. Furthermore, the challenges and opportunities associated with this research area are also discussed.