High-performance AEM unitized regenerative fuel cell using Pt-pyrochlore as bifunctional oxygen electrocatalyst

The performance of fixed-gas unitized regenerative fuel cells (FG-URFCs) are limited by the bifunctional activity of the oxygen electrocatalyst. It is essential to have a good bifunctional oxygen electrocatalyst which can exhibit high activity for oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). In this regard, Pt-Pb₂Ru₂O_7-x is synthesized by depositing Pt on Pb₂Ru₂O_7-x wherein Pt individually exhibits high ORR while Pb₂Ru₂O_7-x shows high OER and moderate ORR activity. Pt-Pb₂Ru₂O_7-x exhibits higher OER (η_@10mAcm-2 = 0.25 ± 0.01 V) and ORR (η_@-3mAcm-2 = -0.31 ± 0.02 V) activity in comparison to benchmark OER (IrO₂, η_@10mAcm-2 = 0.35 ± 0.02 V) and ORR (Pt/C, η_@-3mAcm-2 = -0.33 ± 0.02 V) electrocatalysts, respectively. Pt-Pb₂Ru₂O_7-x shows a lower bifunctionality index (η_{@10mAcm-2, OER}^- η_{@-3mAcm-2, ORR}) of 0.56 V with more symmetric OER-ORR activity profile than both Pt (>1.0 V) and Pb₂Ru₂O_7-x (0.69 V) making it more useful for the AEM (anion exchange membrane) URFC or metal-air battery applications. FG-URFC tested with Pt-Pb₂Ru₂O_7-x and Pt/C as bifunctional oxygen electrocatalyst and bifunctional hydrogen electrocatalyst, respectively, yields a mass-specific current density of 715 ± 11 A/g_cat^-1 at 1.8 V and 56 ± 2 A/g_cat^-1 at 0.9 V under electrolyzer mode and fuel-cell mode, respectively. The FG-URFC shows a round-trip efficiency of 75% at 0.1 A/cm^-2, underlying improvement in AEM FG-URFC electrocatalyst design.