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Electron delocalization refers to the distribution of electrons across multiple atoms within a molecule rather than being confined to a single atom or bond. This phenomenon is common in systems with conjugated bonds—structures where alternating single and double bonds allow π-electrons to move freely across the network. The movement of electrons stabilizes the molecule and can affect various chemical properties, including vibrational frequencies observed in IR spectroscopy.
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Constraint-Induced Delocalization.

Piotr Sierant1,2, Eduardo Gonzalez Lazo1,3, Marcello Dalmonte1,3

  • 1The Abdus Salam International Center for Theoretical Physics, Strada Costiera 11, 34151 Trieste, Italy.

Physical Review Letters
|October 1, 2021
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Summary
This summary is machine-generated.

We investigated how quenched disorder affects quantum spin chains with local constraints. Our findings show that competing disorder effects prevent many-body localization, even under strong disorder conditions.

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Area of Science:

  • Quantum physics
  • Condensed matter physics
  • Disordered quantum systems

Background:

  • Quantum spin chains are fundamental models in condensed matter physics.
  • Rydberg atoms provide a controllable platform for realizing 1D quantum systems.
  • Quenched disorder introduces randomness, potentially leading to novel quantum phenomena like many-body localization.

Purpose of the Study:

  • To investigate the impact of quenched disorder on the dynamics of locally constrained quantum spin chains.
  • To determine if many-body localization occurs in these constrained systems under disorder.
  • To elucidate the competing mechanisms through which disorder affects system dynamics.

Main Methods:

  • Large-scale numerical simulations of 1D quantum spin chains.
  • Analysis of both frozen (Ising-type) and dressed (XY-type) regimes.
  • Detailed examination of quenched disorder terms in constrained systems.

Main Results:

  • No evidence of many-body localization was observed, even with significant disorder.
  • Quenched disorder terms act as both on-site disorder and interactions between excitations.
  • These competing effects prevent the system from reaching the strong disorder, weak interaction regime required for many-body localization.

Conclusions:

  • A competing mechanism involving disorder and interaction prevents many-body localization in constrained quantum spin chains.
  • This understanding can be extended to other constrained models and quenched gauge theories.
  • The interplay between disorder and constraints offers a new perspective on quantum dynamics.