Characteristics of Cu(II)-modified aerobic granular sludge biocarbon in removal of doxycycline hydroxide

In this study, the biocarbon derived from aerobic granular sludge with different nutritive proportions was modified by Cu(NO₃)₂•3H₂O (Cu-BC) to improve its adsorption capacity of doxycycline hydrochloride (DOX). The surface area, pores, functional groups, and element composition of biocarbon were characterized by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) surface area, X-ray photoelectron spectrometer, X-ray diffraction (XRD), the X-ray photoelectron spectrometer, and Fourier transform infrared spectrometry (FT-IR), respectively. Effects of DOX concentration, initial pH, and background electrolyte on adsorption effects of composite were analyzed. Furthermore, the adsorption kinetics, isotherm, thermodynamics, and diffusion model were investigated. Results demonstrated that biocarbons which were prepared with aerobic granular sludge under different nutritive proportions presented different performances. The BET specific surface area of Cu-NaAC/AGS-BC was 260.1592 m²/g, and the micropore volume was 0.054101 cm³/g. The BET specific surface area of Cu-GLC /AGS-BC was only 10.6821 m²/g, and the micropore volume was 0.008687 cm³/g. Both kinds of modified biochar contain a large number of oxygen-containing functional groups. The highest adsorption efficiency of Cu-BC could reach 99.54%. The adsorption of DOX on two modified biocarbons conforms to the pseudo-second-order dynamic model and Temkin isothermal model.