Speciation analysis of inorganic selenium in wastewater using a highly selective cellulose-based adsorbent via liquid...

Speciation of selenium (Se) is typically carried out using a sophisticated technique such as ICP-MS after preconcentration using an adsorbent; however, the separation and preconcentration of inorganic Se has not been realized in the solutions containing high concentrations of SO₄^2-. A dithiocarbamate-modified cellulose (DMC) was used in this study for the selective extraction and preconcentration of inorganic Se in wastewater, with a portable liquid electrode plasma-optical emission spectrometry (LEP-OES) being employed for quantification. DMC was found to selectively and quantitatively adsorb selenite (Se^IV) over a wide range of pH (1.0-8.0); however, less than 3.0% of selenate (Se^VI) was adsorbed in a pH range of 3.0-11. Quantitative extraction of Se^IV was achieved even in the presence of 3.5 mol L^-1 SO₄^2-. The maximum sample volume from which 10 mg of DMC could quantitatively extract Se^IV was found to be 500 mL. KOH (0.60 mL, 1.5 mol L^-1) was found to quantitatively desorb Se^IV retained on the adsorbent and yielded an enrichment factor of 833. The recovery of Se species from synthetic flue-gas desulfurization wastewater containing Se^IV and Se^VI at concentrations of 5.0 µmol L^-1 was 96.2 ± 1.8% and 105.8 ± 1.8%, respectively.