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Updated: Oct 18, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
Published on: November 21, 2017
Highly Active Homoleptic Zinc and Magnesium Complexes Supported by Constrained Reduced Schiff Base Ligands for the
Tanyawan Pongpanit1, Thonthun Saeteaw1, Phongnarin Chumsaeng1
1Department of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Wangchan, Rayong 21210, Thailand.
Abstract:
New homoleptic zinc and magnesium complexes containing constrained reduced Schiff base ligands based on substituted 7-hydroxy-1-indanone were successfully synthesized and used as a catalyst for the polymerization of lactide. The ligands contain a side arm having different basicity because dimethylamino, pyridyl, and furfuryl groups are shown to greatly affect the polymerization rates. The homoleptic zinc complex containing constrained reduced Schiff base ligands and a dimethylamino side arm was highly active, giving a 92% conversion of l-lactide in 3 min using [LA]:[Zn]:[BnOH] = 500:1:2 at room temperature. The polymerization is pseudo-first-order dependent on the LA concentration. Well-controlled and living behavior of the zinc complex was observed and demonstrated in the preparation of stereodiblock and triblock copolymers of l-, d-, and rac-lactide in a one-pot sequential synthesis with a predictable block length, block sequence, and narrow dispersity rapidly in 10 min. Stereocomplex formation was observed for PLA made sequentially from 100 l-LA, 100 rac-LA, and 100 d-LA having a high Tm of up to 220 °C.
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