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A Triazole Functionalized txt-Type Metal-Organic Framework with High Performance for CH4 Uptake and Selective CO2
Mingxing Zhang1, Huihui Cui1, Lifang Zhang1
1School of Chemistry and Chemical Engineering, Nantong University, Nantong, Jiangsu 226019, China.
Inorganic Chemistry
|October 4, 2021
Abstract:
The metal-organic framework (MOF) NTUniv-54 (NTUniv = Nantong University) was assembled via utilizing click chemistry with densely decorated trizole units and exposed metal sites, which exhibited the best methane working ability (197 cm3·cm-3 from 100 to 5 bar and 177 cm3·cm-3 from 65 to 5 bar at 298 K), and the lowest CO2 Qst of 22.8 kJ·mol-1 in all triazole-MOFs at room temperature.

