Tracking of Nanoparticle Diffusion at a Liquid-Liquid Interface Adsorbed by Nonionic Surfactants

Emulsions stabilized by both nanoparticles and surfactants often display longer shelf life than those stabilized by nanoparticles or surfactants alone. Although numerous works have been conducted to understand the effect of nanoparticles and surfactants on the variation of interfacial tension, little is known about interfacial diffusion when both nanoparticles and surfactants are present at interfaces. In this work, we used single-particle fluorescence tracking to study the lateral diffusion of individual hydrophobic nanoparticles at hexane-glycerol interfaces adsorbed by different amounts of nonionic surfactants. When the surfactant concentration is over a threshold, we found that the nanoparticle diffusion exhibits a two-regime behavior involving short-time Brownian and the emergence of subdiffusive, non-Gaussian, and dynamically anticorrelated diffusion in the long lag time regime. A stepwise analysis rationalized diffusion in different lag time regimes, leading to a mechanistic interpretation regarding the two-regime behavior. These results could provide insight into the understanding of the synergistic effect for the surfactant-assistant Pickering emulsion.