Self-Propelled Nanojets for Fenton Catalysts Based on Halloysite with Embedded Pt and Outside-Grafted Fe₃O₄

Taking inspirations from nature, we endeavor to develop catalytically self-propelled nanojets from a type of tubular clay minerals, halloysite nanotubes (HNTs), and utilize them as catalysts targeted for catalysis where the traditional means of mechanical agitation cannot be implemented. Nanojets of Fe₃O₄@HNTs/Pt were prepared by impregnating platinum nanoparticles (Pt NPs) in lumens of HNTs and selective grafting of magnetite (Fe₃O₄) particles on the external surface. The HNT-based nanojets were validated to be highly suitable both in free bulk solution and in microfluidic flow. An example of Fenton degradation catalyzed by these jets was demonstrated. The powerful movement of Fe₃O₄@HNTs/Pt (368 ± 50 μm·s^-1) fueled by 5.0% wt. H₂O₂ was found to follow a bubble propulsion mechanism, and the motion exhibits collective behavior as swarms. The clay tubes were for the first time observed to self-assemble into fish-like aggregates during swimming, reflecting natural occurrence of motion-evolution philosophy. Guided motion was realized by employing magnetic manipulation which makes jets feasible for reactors with complex microchannels/reactors.