A bosonic perspective on the classical mapping of fermionic quantum dynamics

We consider the application of the original Meyer-Miller (MM) Hamiltonian to mapping fermionic quantum dynamics to classical equations of motion. Non-interacting fermionic and bosonic systems share the same one-body density dynamics when evolving from the same initial many-body state. The MM classical mapping is exact for non-interacting bosons, and therefore, it yields the exact time-dependent one-body density for non-interacting fermions as well. Starting from this observation, the MM mapping is compared to different mappings specific for fermionic systems, namely, the spin mapping with and without including a Jordan-Wigner transformation and the Li-Miller mapping (LMM). For non-interacting systems, the inclusion of fermionic anti-symmetry through the Jordan-Wigner transform does not lead to any improvement in the performance of the mappings, and instead, it worsens the classical description. For an interacting impurity model and for models of excitonic energy transfer, the MM and LMM mappings perform similarly, and in some cases, the former outperforms the latter when compared to a full quantum description. The classical mappings are able to capture interference effects, both constructive and destructive, that originate from equivalent energy transfer pathways in the models.