Multifunctional oil-produced reduced graphene oxide - Silver oxide composites with photocatalytic, antioxidant, and...

Graphene-based nanomaterials that combine significant photocatalytic, antioxidant and antibacterial activity are very attractive candidates for biomedical and environmental applications. Conventional chemical synthesis routes may contaminate the resultant materials with toxic molecules, compromising their properties and limiting their use in biomedical applications. Ideally, to avoid any contamination, the nanomaterials should be synthesized from non-toxic precursors and reagents, e.g. foodstuff via a simple technology that does not rely on the use of hazardous chemicals yet produces materials of high quality. Here, we report an environmentally friendly, low cost reduced graphene oxide-silver-silver oxide nanocomposite with strong photocatalytic, antioxidant and antibacterial activity for environmental remediation. The reduced graphene oxide (FRGO) is synthesized from edible sunflower oil via a simple flame synthesis method. Next, silver nanoparticles (Ag/AgO/Ag₂O) are produced by phytochemical reduction of AgNO₃ using a reducing agent based on flavonoids from Coleus aromaticus (Mexican mint), also used in food industry. Thus-obtained FRGO-Ag/AgO/Ag₂O composite is characterized using X-ray diffraction spectroscopy, scanning electron microscopy, fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. The degradation of anionic textile dye Methylene blue (MB) is used as a measure of photocatalytic activity of FRGO and FRGO/Ag/AgO/Ag₂O, with solution pH, initial dye concentration, and quantity of the catalyst considered as influencing factors. FRGO-Ag/AgO/Ag₂O composites show strong antioxidant activity, with improved radical inhibition as well as dye degradation properties when compared to pristine FRGO.