Chrysanthemum-like FeS/Ni₃S₂ heterostructure nanoarray as a robust bifunctional electrocatalyst for overall water...

The development of a scalable strategy to prepare highly efficient and stable bifunctional electrocatalysts is the key to industrial electrocatalytic water splitting cycles to produce clean hydrogen. Here, a simple and quick one-step hydrothermal method was used to successfully fabricate a three-dimensional core chrysanthemum-like FeS/Ni₃S₂ heterogeneous nanoarray (FeS/Ni₃S₂@NF) on a porous nickel foam skeleton. Compared with the monomer Ni₃S₂@NF, the chrysanthemum-like FeS/ Ni₃S₂@NF heterostructure nanomaterials have improved catalytic performance in alkaline media, showing low overpotentials of 192 mV (η₁₀) and 130 mV (η_-10) for OER and HER, respectively. This study attests that integrated interface engineering and precise morphology control are effective strategies for activating the Ni³⁺/Ni²⁺ coupling, promoting charge transfer and improving the intrinsic activity of the material to accelerate the OER reaction kinetics and promote the overall water splitting performance. The scheme can be reasonably applied to the design and development of transition metal sulfide-based electrocatalysts to put into industrial practice of electrochemical water oxidation.