The Application of Hollow Carbon Nanofibers Prepared by Electrospinning to Carbon Dioxide Capture

Coaxial electrospinning has been considered a straightforward and convenient method for producing hollow nanofibers. Therefore, the objective of this study was to develop hollow activated carbon nanofibers (HACNFs) for CO₂ capture in order to reduce emissions of CO₂ to the atmosphere and mitigate global warming. Results showed that the sacrificing core could be decomposed at carbonization temperatures above 900 °C, allowing the formation of hollow nanofibers. The average outer diameters of HACNFs ranged from 550 to 750 nm, with a shell thickness of 75 nm. During the carbonization stage, the denitrogenation reactions were significant, while in the CO₂ activation process, the release of carbon oxides became prominent. Therefore, the CO₂ activation could increase the percentages of N=C and quaternary N groups. The major nitrogen functionalities on most samples were O=C-NH and quaternary N. However, =C and quaternary N groups were found to be crucial in determining the CO₂ adsorption performance. CO₂ adsorption on HACNFs occurred due to physical adsorption and was an exothermic reaction. The optimal CO₂ adsorption performance was observed for HACNFs carbonized at 900 °C, where 3.03 mmol/g (1 atm) and 0.99 mmol/g (0.15 atm) were measured at 25 °C. The degradation of CO₂ uptakes after 10 adsorption-desorption cyclic runs could be maintained within 8.9%.