Effect of Vulcanization and CO₂ Plasticization on Cell Morphology of Silicone Rubber in Temperature Rise Foaming...

Both vulcanization reaction and CO₂ plasticization play key roles in the temperature rise foaming process of silicone rubber. The chosen methyl-vinyl silicone rubber system with a pre-vulcanization degree of 36% had proper crosslinked networks, which not only could ensure enough polymer matrix strength to avoid bubble rupture but also had enough dissolved CO₂ content in silicone rubber for induced bubble nucleation. The CO₂ diffusion and further vulcanization reaction occur simultaneously in the CO₂ plasticized polymer during bubble nucleation and growth. The dissolved CO₂ in the pre-vulcanized silicone rubber caused a temperature delay to start while accelerating further vulcanization reactions, but the lower viscoelasticity caused by either CO₂ plasticization or fewer crosslinking networks was still the dominating factor for larger cell formation. There was a sudden increase in elastic modulus and complex viscosity for pre-vulcanized silicone rubbers at higher temperature because of the occurrence of further vulcanization, but CO₂ plasticization reduced the scope of change of rheological properties, and the loss factor was close to 1 around 170 °C, which is corresponding to the optimum foaming temperature. The foamed silicone rubber had a higher cell density and smaller cell size at a higher temperature rising rate, which is due to higher CO₂ supersaturation and faster vulcanization reaction. These results provide some insight into the coupling mode and effect of CO₂ plasticization and vulcanization for regulating cell structure in foaming silicone rubber process.