Preparation of Bamboo-Based Hierarchical Porous Carbon Modulated by FeCl₃ towards Efficient Copper Adsorption

Using bamboo powder biochar as raw material, high-quality meso/microporous controlled hierarchical porous carbon was prepared-through the catalysis of Fe³⁺ ions loading, in addition to a chemical activation method-and then used to adsorb copper ions in an aqueous solution. The preparation process mainly included two steps: load-alkali leaching and chemical activation. The porosity characteristics (specific surface area and mesopore ratio) were controlled by changing the K₂CO₃ impregnation ratio, activation temperature, and Fe³⁺ ions loading during the activation process. Additionally, three FBPC samples with different pore structures and characteristics were studied for copper adsorption. The results indicate that the adsorption performance of the bamboo powder biochar FBPC material was greatly affected by the meso/micropore ratio. FBPC _2.5-900-2%, impregnated at a K₂CO₃: biochar ratio of 2.5 and a Fe³⁺: biochar mass ratio of 2%, and activated at 900 °C for 2 h in N₂ atmosphere, has a very high specific surface area of 1996 m² g^-1 with a 58.1% mesoporous ratio. Moreover, it exhibits an excellent adsorption capacity of 256 mg g^-1 and rapid adsorption kinetics for copper ions. The experimental results show that it is feasible to control the hierarchical pore structure of bamboo biochar-derived carbons as a high-performance adsorbent to remove copper ions from water.