Synthesis and stabilization of black phosphorus and phosphorene: recent progress and perspectives

Two-dimensional black phosphorus (BP) has triggered tremendous research interest owing to its unique crystal structure, high carrier mobility, and tunable direct bandgap. Preparation of few-layer BP with high quality and stability is very important for its related research and applications in biomedicine, electronics, and optoelectronics. In this review, the synthesis methods of BP, including the preparation of bulk BP crystal which is an important raw material for preparing few-layer BP, the popular top-down methods, and some direct growth strategies of few-layer BP are comprehensively overviewed. Then chemical ways to enhance the stability of few-layer BP are concretely introduced. Finally, we propose a selection rule of preparation methods of few-layer BP according to the requirement of specific BP properties for different applications. We hope this review would bring some insight for future researches on BP and contributes to the acceleration of BP's commercial progress.