Elemental composition of fine and coarse particles across the greater Los Angeles area: Spatial variation and...

The inorganic components of particulate matter (PM), especially transition metals, have been shown to contribute to PM toxicity. In this study, the spatial distribution of PM elements and their potential sources in the Greater Los Angeles area were studied. The mass concentration and detailed elemental composition of fine (PM_2.5) and coarse (PM_2.5-10) particles were assessed at 46 locations, including urban traffic, urban community, urban background, and desert locations. Crustal enrichment factors (EFs), roadside enrichments (REs), and bivariate correlation analysis revealed that Ba, Cr, Cu, Mo, Pd, Sb, Zn, and Zr were associated with traffic emissions in both PM_2.5 and PM_2.5-10, while Fe, Li, Mn, and Ti were affected by traffic emissions mostly in PM_2.5. The concentrations of Ba, Cu, Mo, Sb, Zr (brake wear tracers), Pd (tailpipe tracer), and Zn (associated with tire wear) were higher at urban traffic sites than urban background locations by factors of 2.6-4.6. Both PM_2.5 and PM_2.5-10 elements showed large spatial variations, indicating the presence of diverse emission sources across sampling locations. Principal component analysis extracted four source factors that explained 88% of the variance in the PM_2.5 elemental concentrations, and three sources that explained 86% of the variance in the PM_2.5-10 elemental concentrations. Based on multiple linear regression analysis, the contribution of traffic emissions (27%) to PM_2.5 was found to be higher than mineral dust (23%), marine aerosol (18%), and industrial emissions (8%). On the other hand, mineral dust was the dominant source of PM_2.5-10 with 45% contribution, followed by marine aerosol (22%), and traffic emissions (19%). This study provides novel insight into the spatial variation of traffic-related elements in a large metropolitan area.