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Colloids and Suspensions01:17

Colloids and Suspensions

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
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Recall that a particle in equilibrium is one for which the external forces are balanced. Static equilibrium involves objects at rest, and dynamic equilibrium involves objects in motion without acceleration; but it is important to remember that these conditions are relative. For instance, an object may be at rest when viewed from one frame of reference, but that same object would appear to be in motion when viewed by someone moving at a constant velocity.
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Colloidal precipitates01:09

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The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
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Colloids03:22

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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Van der Waals Interactions01:24

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Atoms and molecules interact with each other through intermolecular forces. These electrostatic forces arise from attractive or repulsive interactions between particles with permanent, partial, or temporary charges. The intermolecular forces between neutral atoms and molecules are ion–dipole, dipole–dipole, and dispersion forces, collectively known as van der Waals forces.
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Newton's first law of motion states that a body at rest remains at rest, or if in motion, remains in motion at constant velocity, unless acted on by a net external force. It also states that there must be a cause for any change in velocity (a change in either magnitude or direction) to occur. This cause is a net external force. For example, consider what happens to an object sliding along a rough horizontal surface. The object quickly grinds to a halt, due to the net force of friction. If...
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Related Experiment Video

Updated: Oct 16, 2025

Quantitative and Qualitative Examination of Particle-particle Interactions Using Colloidal Probe Nanoscopy
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Depletion torques between anisotropic colloidal particles.

Thomas G Mason1

  • 1Department of Chemistry and Biochemistry, University of California-Los Angeles, Los Angeles, California 90095, USA and Department of Physics and Astronomy, University of California-Los Angeles, Los Angeles, California 90095, USA.

The Journal of Chemical Physics
|October 16, 2021
PubMed
Summary
This summary is machine-generated.

Depletion torques influence colloidal particle orientation, extending the Asakura-Oosawa depletion force theory. Tailoring particle shape allows control over these torques for complex colloidal systems.

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Last Updated: Oct 16, 2025

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Area of Science:

  • Colloid and Interface Science
  • Statistical Mechanics
  • Soft Matter Physics

Background:

  • The Asakura-Oosawa model describes depletion forces between spheres due to non-adsorbing polymers or nanoparticles.
  • Experimental studies show microscale plate-like particles form chains influenced by nanoscale depletion agents.
  • Depletion forces can induce torques, affecting the orientation of anisotropic colloidal particles.

Purpose of the Study:

  • To extend the entropic notion of depletion forces to quantify depletion torques on complex-shaped colloidal particles.
  • To investigate how particle geometry influences depletion torques in colloidal dispersions.
  • To explore the potential for designing particle shapes to control their orientation via depletion torques.

Main Methods:

  • Theoretical calculations of depletion torques for various plate-like, prismatic colloidal particles interacting with spherical depletion agents.
  • Analysis of near-contact pair interactions, including parallel and non-parallel configurations.
  • Consideration of particles with diverse symmetries (rotationally symmetric, asymmetric, achiral, chiral, elongated) and hinge-like interactions.

Main Results:

  • Depletion torques were calculated for a wide range of complex-shaped colloidal particles.
  • The study determined depletion torques for non-parallel square platelets connected by a hinge.
  • Results demonstrate that specific geometrical features significantly impact depletion torques.

Conclusions:

  • Depletion torques are a crucial factor in the orientational behavior of complex-shaped colloidal particles.
  • Particle shape and geometry can be engineered to precisely control depletion torques.
  • This work provides a foundation for designing self-assembling colloidal structures with controlled orientations.