Intensity dependence of multiply charged atomic ions from argon clusters in moderate nanosecond laser fields

We report the laser intensity dependence of multiply charged atomic ions (MCAIs) Arⁿ⁺ with 2 ≤ n ≤ 8 from argon clusters in focused nanosecond laser fields at 532 nm. The laser field, in the range of 10¹¹-10¹² W/cm², is insufficient for optical field ionization but is adequate for multiphoton ionization. The MCAI sections of the mass spectra for clusters containing 3700 and 26 000 atoms are dominated by Arⁿ⁺ with 7 ≤ n ≤ 9, extending to Ar¹⁴⁺. While the distributions of the MCAIs remain largely constant throughout the intensity range of the laser, the abundance of Ar⁺ relative to the abundances of the MCAIs increases dramatically with increasing laser intensity. Consequently, exponential fittings of the yields result in a larger exponent for Ar⁺ than for MCAIs, and the exponents of MCAIs with 2 ≤ n ≤ 8 are similar, with only slight variations for different charge states. The width of the arrival time and, hence, the corresponding kinetic energy of Ar⁺ also increases with increasing laser intensities, while the width of the arrival time of MCAIs remains constant throughout the range of measurements. These results call for more detailed theoretical investigations in this regime of laser-matter interactions.