Application of a polymer-magnetic-algae based nano-composite for the removal of methylene blue - Characterization,...

The potential ability of synthesized PPy-Fe₃O₄-SW nano-composite to remove Methylene Blue (MB) from synthetic textile dye solution was investigated under batch conditions. Through parametric studies, the influence of process parameters namely solution pH, on the effective performance of nano-composite was studied. PPy - Fe₃O₄- SW nano-composite removed 99.14% of MB at the optimized conditions of pH-10, temperature - 25 °C, initial MB concentration - 50 mg/L, nano-composite dosage - 20 mg and contact time - 20 min. PPy - Fe₃O₄- SW nano-composite has a maximum sorption capacity of 666.66 mg/g. The kinetics and isotherm study revealed that the chromium adsorption obeys pseudo second order (PSO) model (R² = 0.9941) and Freundlich isotherm (R² = 0.9910) respectively. The PSO kinetic constant (K₂) was found to be 0.000442 (g/mg) min. The thermodynamic feasibility was confirmed through negative values of standard free energy at all tested conditions. The characteristics of adsorption study were analyzed and the results of FTIR, SEM and EDS confirmed the uptake of MB by PPy-Fe₃O₄-SW nano-composite.