Simultaneous removal of NO, SO₂ and Hg⁰ with the WDRMRS

Micro-nanobubbles can spontaneously generate hydroxyl free radicals (OH). Urea is a cheap reductant and can react with NO_x species, and their products are nontoxic and harmless N₂, CO₂ and H₂O. In this study, a Wet Direct Recycling Micro-nanobubble Flue Gas Multi-pollutants Removal System (WDRMRS) was developed for the simultaneous removal of NO, SO₂ and Hg⁰. In this system, a micro-nanobubble generator (MNBG) was used to produce a micro-nanobubble gas-liquid dispersion system (MNBGLS) through recycling the urea solution from the reactor and the simulated flue gas composed of N₂, NO, SO₂ and Hg⁰. The MNBGLS, which has a large gas-liquid dispersion interface, was recycled continuously from the MNBG to the reactor, thus achieving cyclic absorption of various pollutants. All of the investigated parameters, including the initial pH and temperature of the absorbent as well as the concentrations of urea, NO and SO₂ had significant effects on the NO removal efficiency but did not significantly affect the SO₂ removal efficiency, whereas only the initial solution pH and NO concentration affected the Hg⁰ removal efficiency. The analysis results of the reaction mechanism showed that ·OH played a critical role in the removal of various pollutants. After the treatment by this system, the main removal products were Hg⁰ sediment, $$ and NH4+ which could be easily recycled. The use of this system (MNBGLS) for the simultaneous removal of NO, SO₂ and Hg⁰ is a new technology application and research. Recycling process based on MNBGLS succeeded in simultaneously removing NO, SO₂ and Hg⁰. The system (MNBGLS) can provide a reference for commercial applications. The removal products are relatively simple and beneficial to recycling, which can reduce the cost of waste gas treatment.