Synthesis of a Dual-Functional Nanofertilizer by Embedding ZnO and CuO Nanoparticles on an Alginate-Based Hydrogel

Recent scientific breakthroughs in the field of agriculture have led to the abundant usage of nanoparticles in agrochemicals to maintain proper nutrient uptake in plants. Since less attention has been given to the supply of vital micronutrients to crop plants, the objective of this study was to develop a nanofertilizer capable of releasing micronutrients while nourishing its surrounding soil. As the initial nanonutrients, Zn and Cu were used in their metal oxide forms, which promote seed germination. Alginic acid was used as the agent responsible for soil conditioning. To form the fertilizing complex, nanoparticles were reacted with sodium alginate, which resulted in a hydrogel where alginate chains were cross-linked with Zn(II) and Cu(II) and excess metal oxide nanoparticles were distributed on the hydrogel. Spectroscopic characterization of the nanofertilizer confirmed that alginate chains were cross-linked by Zn(II) and Cu(II), while morphological analysis by scanning electron microscopy (SEM) showed that ZnO and CuO nanoparticles were embedded on the alginate matrix. The release behavior of cations in soil and water environments, experimented using the tea bag method, revealed that the cationic release was slowly increasing with time. Micronutrient uptake by plants was studied by conducting leaf analyses in tomato plants for 30 consecutive days. To experiment the release behavior of micronutrients in the presence of compost, the nanofertilizer was added with predetermined amounts of compost to tomato plants. Flame atomic absorption spectroscopy (FAAS) results indicated that in the fertilizer-applied plants, Cu concentrations showed a steady increase with time while Zn concentrations remained undetected.