Fabrication of novel bio-adsorbent and its application for the removal of Cu(II) from aqueous solution

As eco-friendly adsorption material, hydroxyapatite (Ca₅(PO₄)₃OH, HA) has been extensively applied to the removal of heavy metal ions. However, separating and recovering of HA powder after the adsorption process limits their application. Alginate-based composite beads (HCA) encapsulated with HA and cellulose were designed to remove Cu(II) from aqueous solution. Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) were used for characteristic analysis. An extensive discussion in terms of HCA adsorption capacity, effect of various Cu(II) concentration, and analysis of the involved mechanisms of Cu(II) removal on the biosorption. HCA beads showed that the maximum adsorption capacity for Cu(II) of 64.14 mg/g at pH = 5 with 8 h contact time. The Langmuir adsorption isotherm and second-order kinetic model gave the closest fit. HCA beads display good regeneration ability after four cycles and offer potentiality for practical application.