Visible Light-Driven D-A Conjugated Linear Polymer and Its Coating for Dual Highly Efficient Photocatalytic...

Herein, a novel donor-acceptor (D-A) conjugated linear polymeric system, poly[(2,6-(4,8-bis(5-(2-ethylhexyl)-4-fluorothiophen-2-yl)-benzo[1,2-b:4,5-b']dithiophene))-alt-2,5-(3-carboxyl)-thiophene] (PBDT-F-COOH), with outstanding processing ability and its all-organic PBDT-F-COOH coating featuring chemical bonding for combination with polyurethane were prepared. Wide visible spectrum-driven PBDT-F-COOH and PBDT-F-COOH-PU showed dual efficient photocatalytic activities toward degradation and disinfection, mainly attributing to efficient dissociation of excitons and transfer of charge carriers, resulting from the large dipole moment of D-A PBDT-F-COOH. PBDT-F-COOH demonstrated >99.2% inactivation of Staphylococcus aureus (S. aureus) within 1 h and a 7-log decrease in 4 h under visible light irradiation. Additionally, the coating showed the 7-log inactivation of S. aureus in 7 h. These inactivation efficiency results are among those of the best reported D-A conjugated linear polymers. Importantly, PBDT-F-COOH and the PBDT-F-COOH-PU coating both presented satisfactory stability with high photocatalytic activity after recycling runs. This work provides a feasible approach for fabricating nontoxic and highly active organic photocatalysts with wide visible spectra and a large dipole moment via a D-A linear structure design protocol.