TiO₂-CeO₂/g-C₃N₄ S-scheme heterostructure composite for enhanced photo-degradation and hydrogen evolution performance...

The g-C₃N₄/TiO₂ nanocomposites (NCs) are fabricated by optimization of calcination and subsequent hydrothermal technique decorated with CeO₂ nanoparticles (NPs) to build the g-C₃N₄/TiO₂-CeO₂ hybrid NCs. The chemical and surface characterizations of structural, morphological, elemental composition, optical, photo-degradation, HER performance and the DFT computation has been efficiently analyzed. The g-C₃N₄/TiO₂-CeO₂ composite photocatalysts (PCs) exhibit photocatalytic improved performance (∼97 %) for MB aqueous dye related to pristine g-C₃N₄ and g-C₃N₄/TiO₂ composite PCs. The obtained k value of the g-C₃N₄/TiO₂/CeO₂ heterostructure composite PCs has around 0.0262 min^-1 and 6.1, 2.6 and 1.5 times higher than to g-C₃N₄ (0.0043 min^-1), g-C₃N₄/CeO₂ (0.0099 min^-1) and g-C₃N₄/TiO₂ (0.0180 min^-1) PCs respectively. Likewise, the synergistic probable S-scheme charge separation mechanism based on scavengers' tests and other values, which leads to effective separation of photo-excited (e^--h⁺) pairs, whereas high degradation and more H₂O molecules have photo-reduction to H₂. The H₂ evolution reaction (HER) and the electrochemical impedance spectroscopy (EIS) of the as-obtained samples were explored via electrochemical study. This exertion recommends that the rational strategy and building of g-C₃N₄/TiO₂-CeO₂ nano-heterostructures were beneficial for developing visible-light-driven recyclable PCs for ecological refinement.