A Multiphysics Peridynamic Model for Simulation of Fracture in Si Thin Films during Lithiation/Delithiation Cycles

Material failure is the main obstacle in fulfilling the potential of electrodes in lithium batteries. To date, different failure phenomena observed experimentally in various structures have become challenging to model in numerical simulations. Moreover, their mechanisms are not well understood. To fill the gap, here we develop a coupled chemo-mechanical model based on peridynamics, a particle method that is suitable for simulating spontaneous crack growth, to solve the fracture problems in silicon thin films due to lithiation/delithiation. The model solves mechanical and lithium diffusion problems, respectively, and uses a coupling technique to deal with the interaction between them. The numerical examples of different types of Si films show the advantage of the model in this category and well reproduce the fracture patterns observed in the experiments, demonstrating that it is a promising tool in simulating material failure in electrodes.