Simple Self-Assembly Strategy of Nanospheres on 3D Substrate and Its Application for Enhanced Textured Silicon Solar...

Nanomaterials and nanostructures provide new opportunities to achieve high-performance optical and optoelectronic devices. Three-dimensional (3D) surfaces commonly exist in those devices (such as light-trapping structures or intrinsic grains), and here, we propose requests for nanoscale control over nanostructures on 3D substrates. In this paper, a simple self-assembly strategy of nanospheres for 3D substrates is demonstrated, featuring controllable density (from sparse to close-packed) and controllable layer (from a monolayer to multi-layers). Taking the assembly of wavelength-scale SiO₂ nanospheres as an example, it has been found that textured 3D substrate promotes close-packed SiO₂ spheres compared to the planar substrate. Distribution density and layers of SiO₂ coating can be well controlled by tuning the assembly time and repeating the assembly process. With such a versatile strategy, the enhancement effects of SiO₂ coating on textured silicon solar cells were systematically examined by varying assembly conditions. It was found that the close-packed SiO₂ monolayer yielded a maximum relative efficiency enhancement of 9.35%. Combining simulation and macro/micro optical measurements, we attributed the enhancement to the nanosphere-induced concentration and anti-reflection of incident light. The proposed self-assembly strategy provides a facile and cost-effective approach for engineering nanomaterials at 3D interfaces.