Recent Advances in Fabrication of Flexible, Thermochromic Vanadium Dioxide Films for Smart Windows

Monoclinic-phase VO₂ (VO₂(M)) has been extensively studied for use in energy-saving smart windows owing to its reversible insulator-metal transition property. At the critical temperature (T_c = 68 °C), the insulating VO₂(M) (space group P21/c) is transformed into metallic rutile VO₂ (VO₂(R) space group P42/mnm). VO₂(M) exhibits high transmittance in the near-infrared (NIR) wavelength; however, the NIR transmittance decreases significantly after phase transition into VO₂(R) at a higher T_c, which obstructs the infrared radiation in the solar spectrum and aids in managing the indoor temperature without requiring an external power supply. Recently, the fabrication of flexible thermochromic VO₂(M) thin films has also attracted considerable attention. These flexible films exhibit considerable potential for practical applications because they can be promptly applied to windows in existing buildings and easily integrated into curved surfaces, such as windshields and other automotive windows. Furthermore, flexible VO₂(M) thin films fabricated on microscales are potentially applicable in optical actuators and switches. However, most of the existing fabrication methods of phase-pure VO₂(M) thin films involve chamber-based deposition, which typically require a high-temperature deposition or calcination process. In this case, flexible polymer substrates cannot be used owing to the low-thermal-resistance condition in the process, which limits the utilization of flexible smart windows in several emerging applications. In this review, we focus on recent advances in the fabrication methods of flexible thermochromic VO₂(M) thin films using vacuum deposition methods and solution-based processes and discuss the optical properties of these flexible VO₂(M) thin films for potential applications in energy-saving smart windows and several other emerging technologies.