Related Experiment Video
Updated: Oct 15, 2025

An Inverse Analysis Approach to the Characterization of Chemical Transport in Paints
Published on: August 29, 2014
Using an alternatives assessment framework to evaluate waterborne versus solventborne basecoats used in automotive
Lawrence A Brown1, Grace Fisk2, Martin A Cohen3
1Hazardous Waste Management Program in King County, Public Health-Seattle & King County, Seattle, Washington, USA.
Abstract:
We evaluated two types of automotive basecoats used in automotive refinishing (i.e., in auto body shops): waterborne and solventborne. The primary tool we used for this evaluation was the Alternatives Assessment Guide (version 1.0) developed by the Interstate Chemicals Clearinghouse (IC2). The term "solventborne," as used in this article, refers to products that contain relatively high concentrations of volatile organic compounds (referred to as "high-volatile organic compound [VOC] basecoats" in the industry). These products are distinct from the "low-VOC" solventborne products used widely in California and elsewhere. From a health and environmental hazard perspective, our evaluation found that waterborne basecoats contained fewer hazardous ingredients and at lower concentrations than their solventborne counterparts. Automotive painters who spray-painted vehicles with waterborne products experienced significantly lower exposures to several harmful solvents. Waterborne products are readily available and offer advantages with regard to social impacts. Some of these advantages include lower worker and community exposure to VOCs, reduced VOC release and smog formation, and reduced potential for generation of and exposure to hazardous waste. Based on our assessment in auto body shops, we consider waterborne basecoats to be safer alternatives from both a human health and environmental perspective. Integr Environ Assess Manag 2022;18:1101-1113. Published 2021. This article is a U.S. Government work and is in the public domain in the USA.
Related Concept Videos
Titration in Nonaqueous Solvents
Leveling Effect
Leveling Effect and Non-Aqueous Acid-Base Solutions
The Leveling Effect of a Solvent
A generic acid (HA) reacts with the generic base (B-) to yield the corresponding conjugate base (A-) and conjugate acid (HB):
Solvents
A...
Factors Affecting α-Alkylation of Ketones: Choice of Base
The reaction involving bases like EtO− whose conjugate acid EtOH (pKa = 15.9) is stronger than the ketone (pKa = 19.2) results in an equilibrium mixture with higher ketone concentration. As a consequence,...
Preparation of Alcohols via Substitution Reactions
Alcohols can be synthesized from alkyl halides via nucleophilic substitution reactions. The highly polar carbon-halogen bond in the substrate makes halide a good leaving group. The hydroxide ion or water can act as a nucleophile to take the place of halide and form an alcohol. The substitution reactions occur via two different reaction pathways, SN1 or SN2, depending on the nature of carbon attached to the halide.
Primary alcohols are synthesized from primary alkyl halides, and the...

