Constructing urchin-like Ni₃S₂@Ni₃B on Ni plate as a highly efficient bifunctional electrocatalyst for water...

Developing efficient and promising non-noble catalysts that can promote both the HER and OER in the same electrolyte is vital. Currently, these reported bifunctional catalysts show only moderate electrocatalytic water-splitting performance, which is much lower than expected. In addition, most of these promising nonprecious electrocatalysts work well only at small current densities (e.g. 10 mA cm^-1), but at large current densities their stability and activity are far from satisfactory for practical applications. Herein, we have successfully constructed an urchin-like Ni₃S₂@Ni₃B heterostructure electrocatalyst on Ni plates. The resulting material exhibits great catalytic activities for both the HER and OER, even at large current densities, reaching a current density of 1000 mA cm^-l at relatively low applied overpotentials of 517 and 632 mV, respectively. The excellent catalytic performance of Ni₃S₂@Ni₃B/NP is found to benefit from the effective integration of the unique surface structure and the interface electronic structure.