Rheological behavior of nanocellulose gels at various calcium chloride concentrations

In this work, the effects of calcium chloride (CaCl₂) concentration on the creep-recovery, linear and nonlinear rheological behavior of nanocellulose gels had been investigated to quantify gel properties. The absolute zeta potential of nanocellulose gels were decreased as the CaCl₂ concentration increased, which was related to the electrostatic repulsion that origin from carboxyl group could be effectively screened with increasing CaCl₂ concentration. Rheological measurements further confirmed this result for nanocellulose gels, which revealed that the increased modulus and viscoelastic properties were obtained in the presence of CaCl₂. The rheological properties of nanocellulose gels were showed to depend on CaCl₂ concentration. The enhanced gel network structure was related to the Ca²⁺ ions that promoted crosslink between nanocellulose by salt bridge. This work highlighted the potential of using electrostatic complexation between nanocellulose and Ca²⁺ ions to form gels, and demonstrated the tunability of the rheological behavior by adjusting the concentration of CaCl₂.