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Binary Plasmonic Assembly Films with Hotspot-Type-Dependent Surface-Enhanced Raman Scattering Properties.

Shuang Lin1, Haoyu Guan1, Yuqi Liu1

  • 1Key Laboratory of New Energy and Rare Earth Resource Utilization of State Ethnic Affairs Commission, Key Laboratory of Photosensitive Materials&Devices of Liaoning Province, School of Physics and Materials Engineering, Dalian Minzu University, Dalian 116600, China.

ACS Applied Materials & Interfaces
|October 27, 2021
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Summary

Controlling plasmon coupling in gold nanostructures enhances optical responses. A novel assembly of gold nanospheres and nanocubes created tunable "hot spots" for superior surface-enhanced Raman scattering (SERS) detection.

Keywords:
binary assemblyfilmhotspot typeplasmonicsurface-enhanced Raman scattering

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Area of Science:

  • Nanotechnology
  • Materials Science
  • Physical Chemistry

Background:

  • Controlling plasmon coupling in noble metal nanoparticles is crucial for optimizing near-field and far-field optical responses.
  • Heterogeneous plasmonic assemblies offer tunable properties for advanced applications.

Purpose of the Study:

  • To propose and fabricate a novel heterogeneous plasmonic assembly with controllable hot spot configurations.
  • To investigate the impact of different hot spot conformations on localized surface plasmon resonance (LSPR) and surface-enhanced Raman scattering (SERS) performance.

Main Methods:

  • Co-assembly of gold nanospheres (Au NS) and gold@silver core-shell nanocube (Au@Ag NC) films.
  • Fabrication of three distinct hot spot configurations (point-to-point, point-to-facet, facet-to-facet) by adjusting nanoparticle doping ratios.
  • Finite-difference time-domain (FDTD) simulations to analyze plasmon coupling and electric field enhancement.

Main Results:

  • The study successfully fabricated heterogeneous plasmonic assemblies with tunable hot spot configurations.
  • Distinct LSPR properties and SERS performance were observed across different hot spot types.
  • The point-to-facet hot spot configuration demonstrated the most significant SERS enhancement compared to single-component assemblies.
  • The developed assemblies showed high sensitivity and reproducibility in identifying ketamine.

Conclusions:

  • Adjusting the doping ratio of nanoparticles in co-assembled films provides a simple method to control hot spot configurations.
  • Heterogeneous plasmonic assemblies with optimized hot spot designs significantly enhance SERS activity.
  • This work presents a new strategy for fabricating plasmonic materials with collective LSPR and sensitive SERS capabilities for molecular detection.