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Updated: Oct 15, 2025
Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
Published on: September 19, 2020
Modification of the three-dimensional graphene aerogel self-assembled network using a titanate coupling agent and its
Sufei Cui1, Wei Wu1,2, Chao Liu1
1Sino-German Joint Research Center of Advanced Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, 200237, PR China. wuwei@ecust.edu.cn.
Abstract:
Three-dimensional thermally conductive graphene aerogels have become more and more significant in practical thermal management applications. However, the interface between the graphene aerogel and the polymer has a strong interface thermal resistance, and the compatibility between the interfaces is also poor. In this study, a simple and versatile method for grafting graphene aerogels with titanate coupling agents on the surface was developed so that the modified graphene aerogels exhibit excellent thermal conductivity and mechanical properties and reduce the interface thermal resistance and increase the interface compatibility between graphene aerogels and epoxy resin. A high thermal conductivity of 2.53 W m-1 K-1 was obtained under a low graphene load of 2.5 wt%, corresponding to a thermal conductivity enhancement of approximately 1388% compared with pure epoxy resin. It provides a facile new idea for the preparation of high-quality three-dimensional graphene epoxy composites.
