Investigation of PEG directed Sb₂WO₆ for dyes removal from wastewater

Pristine and polyethylene glycol assisted antimony tungstate (Sb₂WO₆) was developed via hydrothermal route. The pristine and surfactant assisted Sb₂WO₆ were further exemplified to reveal the properties of the samples. The bandgap calculated for Sb₂WO₆, 5 ml PEG- Sb₂WO₆, 10 ml PEG- Sb₂WO₆ was 2.78 eV, 2.66 eV and 2.21 eV. The 10 ml PEG assisted sample exhibited narrow bandgap. The Fourier transform infrared spectroscopy (FTIR) spectra of the samples showed metal vibrations and stretching of the water molecules adsorbed. The Raman spectra showed the vibrational modes present in Sb₂WO₆. The morphology was analyzed employing transmission electron microscope (TEM) for all samples. Pristine Sb₂WO₆ showed growth of nanorods with higher dimensions with high agglomeration. 5 ml PEG- Sb₂WO₆ showed the growth of nanorods with lesser agglomeration. 10 ml PEG assisted Sb₂WO₆ exhibited distinct growth of nanorods with no agglomeration on the surface. The elemental composition was examined employing X-ray Photoelectron Spectroscopy. Prepared product photocatalytic behaviour was tested employing Rhodamine B dye degrading. Different catalyst loading were investigated for degrading the toxic pollutants. 0.2 g 10 ml PEG-Sb₂WO₆ showed 81% efficiency on degrading the toxic pollutant from wastewater. The OH radicals are accountable for photocatalytic behaviour of prepared photocatalyst. The 10 ml PEG-Sb₂WO₆ has the good reusability behavior and stable properties after three cycles. The prepared 10 ml PEG- Sb₂WO₆ photocatalyst will be the potential candidate for the remediation of the water treatment.