Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Cationic Chain-Growth Polymerization: Mechanism00:57

Cationic Chain-Growth Polymerization: Mechanism

2.5K
The cationic polymerization mechanism consists of three steps: initiation, propagation, and termination. In the initiation step of the polymerization process, the π bond of a monomer gets protonated by the Lewis acid catalyst, which is formed from boron trifluoride and water. The protonation of the π bond generates a carbocation stabilized by the electron‐donating group. In the propagation step, the π bond of the second monomer acts as a nucleophile and attacks the...
2.5K
Step-Growth Polymerization: Overview01:03

Step-Growth Polymerization: Overview

3.8K
Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
Many natural and synthetic polymers are produced by...
3.8K
Ziegler–Natta Chain-Growth Polymerization: Overview01:17

Ziegler–Natta Chain-Growth Polymerization: Overview

3.5K
Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta...
3.5K
Olefin Metathesis Polymerization: Overview01:13

Olefin Metathesis Polymerization: Overview

2.3K
Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...
2.3K
Characteristics and Nomenclature of Copolymers01:24

Characteristics and Nomenclature of Copolymers

2.9K
Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...
2.9K
Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)

2.0K
Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
2.0K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Interface Engineering: Heterogeneous Nickel-Iron Sulfide Decorated Nitrogen-Doped-Graphene for Efficient Water Splitting.

ChemSusChem·2026
Same author

Upcycling Commodity Polymers into Semiconductors by Sequential Grafting of Aromatic Units through Regioselective Iodination and Living Suzuki-Miyaura Catalyst-Transfer Polymerization.

Journal of the American Chemical Society·2026
Same author

Development of whey protein-derived aerogel microcarriers for cultivated meat production.

Food chemistry·2026
Same author

Direct Polymer-on-Polymer Grafting of Polyolefins under Visible Light.

Journal of the American Chemical Society·2026
Same author

Adjusting the local coordination microenvironment of single atoms to optimize catalytic efficiency in renewable energy devices.

Chemical communications (Cambridge, England)·2026
Same author

Mechanically Triggered Chemical Recyclable Polyethylene-Like Materials.

Angewandte Chemie (International ed. in English)·2026
Same journal

Reprocessable Disulfide-Based Vitrimers with Adhesive Properties.

Macromolecular rapid communications·2026
Same journal

Micro- and Nanopatterning of Highly Conductive PEDOT Thin Films.

Macromolecular rapid communications·2026
Same journal

From Molecular Structure to Macroscopic Performance: Insights into Polycarbosilane Curing.

Macromolecular rapid communications·2026
Same journal

High-Yield Synthesis of Molecular Bottlebrushes With Block Copolymer Side Chains by the Copper Superoxido Complex Enabled ATRP via a Grafting-From Approach.

Macromolecular rapid communications·2026
Same journal

Chemically and Mechanically Recyclable Polyolefins Incorporating Covalent Adaptable Networks.

Macromolecular rapid communications·2026
Same journal

Designing Thermally Stable DNA Hydrogels via Entropically-Driven Acridine Intercalation.

Macromolecular rapid communications·2026
See all related articles

Related Experiment Video

Updated: Oct 15, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
05:48

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

8.2K

Recent Advances in Diversity-Oriented Polymerization Using Cu-Catalyzed Multicomponent Reactions.

In-Hwan Lee1, Ki-Taek Bang2, Hee-Seong Yang3

  • 1Department of Chemistry, Ajou University, Suwon, 16499, Korea.

Macromolecular Rapid Communications
|October 29, 2021
PubMed
Summary
This summary is machine-generated.

Diversity-oriented polymerization (DOP) enables novel polymer applications. Copper-catalyzed multicomponent polymerization (Cu-MCP) is a key advancement, overcoming previous synthetic challenges for complex polymer structures.

Keywords:
Cu-catalyzed multicomponent polymerizationCu-catalyzed multicomponent reactiondiversity-oriented polymerization

More Related Videos

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
11:42

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers

Published on: June 20, 2019

8.0K
Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
07:28

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization

Published on: November 27, 2015

13.4K

Related Experiment Videos

Last Updated: Oct 15, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
05:48

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Published on: November 21, 2017

8.2K
Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
11:42

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers

Published on: June 20, 2019

8.0K
Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
07:28

Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization

Published on: November 27, 2015

13.4K

Area of Science:

  • Polymer Chemistry
  • Organic Synthesis

Background:

  • Polymer structure diversification is crucial for developing advanced materials with tailored properties.
  • Diversity-oriented polymerization (DOP) is a strategic approach to synthesize complex and varied polymer architectures.
  • Multicomponent polymerization (MCP) offers an efficient and combinatorial route to achieve DOP.

Purpose of the Study:

  • To review the emergence and progress of copper-catalyzed multicomponent polymerization (Cu-MCP).
  • To highlight Cu-MCP as a pivotal method for diversity-oriented polymerization.
  • To discuss the current challenges and future outlook of Cu-MCP.

Main Methods:

  • Focuses on Cu-catalyzed multicomponent polymerization (Cu-MCP) techniques.
  • Discusses the synthetic strategies and advantages of Cu-MCP for polymer diversification.
  • Reviews advancements in overcoming limitations of prior MCP methods.

Main Results:

  • Cu-MCP has emerged as a powerful tool for synthesizing diverse polymer structures.
  • This method addresses synthetic challenges inherent in earlier multicomponent polymerization approaches.
  • Cu-MCP facilitates the creation of complex polymers essential for novel applications.

Conclusions:

  • Copper-catalyzed multicomponent polymerization (Cu-MCP) is a significant breakthrough in diversity-oriented polymerization.
  • The methodology offers enhanced efficiency and combinatorial possibilities for polymer synthesis.
  • Future research should address current challenges to further expand the scope and application of Cu-MCP.