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Updated: Oct 14, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Synthesis and Selective Au(III) Adsorption of Ureido Polymers Containing Large Repeating Rings
Yunkai Sun1,2, Yaqian Ding1, Wenwen Zhou1
1School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China.
Abstract:
Two polymers (polyBAUEE and polyBAUP) containing 25- and 20-membered rings are synthesized by the cyclopolymerization of bifunctional monomers 1,2-bis(acryloyloxyethyl-ureidoethoxyl)-ethane (BAUEE) and 1,3-bis(acryloyloxyethylureido)propane (BAUP) and studied for the adsorption of precious metal ions. PolyBAUEE and polyBAUP selectively adsorb Au(III) with the adsorption efficiencies above 99.0% after adsorption equilibrium. PolyBAUEE adsorbed faster than polyBAUP, and the Au(III) adsorption is selective in the presence of nine interfering metal ions with similar concentrations (ca. 1 mg/L) in an aqueous solution including Pd(II) and Pt(II). The maximum Au(III) adsorption capacities of polyBAUEE and polyBAUP are 37.6 and 31.8 mg/g, respectively. Au(III) is reduced to Au(0) nanoparticles during the adsorption process. The selective adsorption behavior depends on the controlling regioselective recognition of the ring structure and the ureido groups.
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