Vibrationally excited molecular hydrogen production from the water photochemistry

Vibrationally excited molecular hydrogen has been commonly observed in the dense photo-dominated regions (PDRs). It plays an important role in understanding the chemical evolution in the interstellar medium. Until recently, it was widely accepted that vibrational excitation of interstellar H₂ was achieved by shock wave or far-ultraviolet fluorescence pumping. Here we show a further pathway to produce vibrationally excited H₂ via the water photochemistry. The results indicate that the H₂ fragments identified in the O(¹S) + H₂(X¹Σ_g⁺) channel following vacuum ultraviolet (VUV) photodissociation of H₂O in the wavelength range of λ = ~100-112 nm are vibrationally excited. In particular, more than 90% of H₂(X) fragments populate in a vibrational state v = 3 at λ~112.81 nm. The abundance of water and VUV photons in the interstellar space suggests that the contributions of these vibrationally excited H₂ from the water photochemistry could be significant and should be recognized in appropriate interstellar chemistry models.