Porous Ga₂ O₃ Nanotubes Derived from Urease-Mediated Interfacially-Grown NH₄ Ga(OH)₂ CO₃ for High-Efficient Hydrogen...

The authors proposed a novel template-free strategy, urease-mediated interfacial growth of NH₄ Ga(OH)₂ CO₃ nanotubes at 20-50 °C, to fabricate the porous Ga₂ O₃ nanotubes. The subtlety of the proposed strategy is all the products from urea enzymolysis are utilized in formation of NH₄ Ga(OH)₂ CO₃ precipitates, and the key for interfacial growth of NH₄ Ga(OH)₂ CO₃ nanotubes is the dynamic match between the rate of CO₂ bubble fusion and NH₄ Ga(OH)₂ CO₃ precipitation. The proposed strategy works well for the doped porous Ga₂ O₃ nanotubes. As a proof-of-concept, the porous β-Ga₂ O₃ and β-Ga₂ O₃ :Cr_0.001 nanotubes are used as photocatalysts or co-catalysts with Pt, for H₂ evolution from water splitting. The H₂ evolution rate of porous β-Ga₂ O₃ nanotubes reach 39.3 mmol g^-1 h^-1 with solar-to-hydrogen (STH) conversion efficiency of 2.11% (Hg lamp) or 498 µmol g^-1 h^-1 with STH of 0.03% (Xe lamp) respectively, both about 3 times of β-Ga₂ O₃ nanoparticles synthesized at pH 9.0 without urease. The Cr-doping enhances the in-the-dark H₂ evolution rate pre-lighted by Hg lamp, and Pt co-catalysis further elevates the H₂ evolution rate, for instance, the H₂ evolution rate of Pt-loaded β-Ga₂ O₃ :Cr_0.001 nanotubes reaches 54.7 mmol g^-1 h^-1 with STH of 2.94% under continuous lighting of Hg lamp and 1062 µmol g^-1 h^-1 in-the-dark.