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Updated: Oct 14, 2025
Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Five Dinuclear Lanthanide Complexes Based on 2,4-dimethylbenzoic Acid and 5,5'-dimethy-2,2'-bipyridine: Crystal
Jia-Yuan Zhao1, Ning Ren2, Ying-Ying Zhang3
1College of Chemistry and Materials Science, Testing and Analysis Center, Hebei Normal University, Shijiazhuang, China.
Abstract:
A series of new complexes, [Ln (2,4-DMBA)3(5,5'-DM-2,2'-bipy)]2 (Ln = Sm(1), Eu (2)), [Pr (2,4-DMBA)3 (5,5'-DM-2,2'-bipy)]2·0.5(C2H5OH) (3), [Ln (2,4-DMBA)3 (5,5'-DM-2,2'-bipy)]2·0.5(2,4-DMBAH)·0.25(5,5'-DM-2,2'-bipy) (Ln = Tb (4), Dy (5)) (2,4-DMBA = 2,4-dimethylbenzoate, 5,5'-DM-2,2'-bipy = 5,5'-dimethy-2,2'-bipyridine) were synthesized via hydrothermal reaction conditions. The complexes were characterized through elemental analysis, Infrared spectra (IR), Raman (R) spectra, UV-Vis spectra, single X-ray diffraction. Single crystal data show that complexes 1-5 are binuclear complexes, but they can be divided into three different crystal structures. The thermal decomposition mechanism of complexes 1-5 were investigated by the technology of simultaneous TG/DSC-FTIR. What's more, the luminescent properties of complexes 1-2 and 4 were discussed, and the luminescence lifetime (τ) of complexes 2 and 4 were calculated.
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