Simulation of cathode for synthesizing organic acids by MES reduction of CO₂

Microbial electrochemical system (MES) is a favorable tool for CO₂ emission reduction. Microbial cathode is one of the core components of the system, and its surface energy transfer characteristics can greatly affect the yield of organic matter from MES. In order to solve the problem that the energy transfer characteristics of microbial cathode are not clear, the mathematical model of MES was constructed on the basis of the preliminary experiment with an electrode made of copper foam modified with the reduced graphene oxide, analyzing the current and substrate concentration in the biofilm with conductivity, cathode potential and porosity of the biofilm. The results show that when the cathode potential is higher than -0.8 V (VS SHE), the substrate concentration and current density in the biofilm are related to the cathode potential. However, when the cathode potential decreased to -0.8 V (vs SHE), the ability of biofilm to reduce CO₂ basically reached saturation. Low conductivity (<10^-3S/m) will lead to the formation of significant potential difference in the biofilm, which will reduce the substrate utilization rate and seriously affect the performance of microbial cathode. The current density is highest, when the porosity of the biofilm is about 0.35.