Development of porous material via chitosan-based Pickering medium internal phase emulsion for efficient adsorption...

The radioactive Rb⁺, Cs⁺ and Sr²⁺ have serious threat for the aquatic life and human health, its removal has been granted increasing concern. Hence the adsorbent with excellent adsorption performance and favourable reusability is strongly demanded. This work prepared a novel porous polymer of chitosan-g-polyacrylamide (CTS-g-PAM) by grafting the acrylamide (AM) onto the chitosan (CTS) with sufficient pore structure via an eco-friendly surfactant-free (corn oil)-in-water Pickering medium internal phase emulsion (O/W Pickering MIPE), solely stabilized by CTS. Interestingly, its pore structure could be tuned by varying the emulsion character via changing the molecular weight and concentration of CTS, as well as the pH values. Due to the abundant -COO^- and -NH₂ functional groups in the porous material of CTS-g-PAM, the high adsorption capacities of 195.43, 237.44 and 185.63 mg/g for Rb⁺, Cs⁺ and Sr²⁺ could be reached within 40, 30 and 20 min, respectively. Moreover, the CTS-g-PAM had excellent regeneration ability and reusability. Herein, we provided a feasible and low-cost pathway for preparation of the porous adsorbent with tunable porous structure for adsorption and separation application.