Economic affordable carbonized phenolic foam anode with controlled structure for microbial fuel cells

In microbial fuel cells (MFCs), the anode electrode is a core structure as the catalytic area of exoelectrogens. The anode material for large-scale MFCs needs excellent bioelectrochemical performance and low fabrication costs. Herein, carbonized phenolic foam with controllable porous structures was developed as the bio-capacitor of MFCs. The proportion of sodium dodecylbenzene sulfonate (SDBS), which improved mixing and dissolution between the resin liquid and the foaming agent, was adjusted to form open pores on the foam film and skeletons, which promoted both the capacitance and biocompatibility of the anode. Within SDBS proportion from 0 to 1.2 wt%, the anode SPF-9 (0.9 wt%) obtained the best capacitance (37 ± 0.13 F g^-1), electrochemical active surface area (87 ± 0.38 cm²) and hydrophilia (contact angle 79 ± 0.2°). The MFCs with SPF-9 obtained the highest power density of 3980 ± 178 mW m^-2, while those of carbon-cloth anodes were 1600 ± 28 mW m^-2. The biofilm of SPF-9 also demonstrated higher activity and obtained larger abundance of exoelectrogens (68 ± 0.38%). The increased capacitance and biocompatibility mainly resulted in the good performance of SPF-9. The carbonized phenolic foam anode material was worth considering for the future application of MFCs due to its superior electrochemical performance and large-quantity fabrication capability.