Related Experiment Video
Updated: Oct 13, 2025

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
Synthesis, structure and bonding nature of heavy dipnictene radical anions
Hanns M Weinert1, Christoph Wölper1, Julia Haak1,2
1Institute for Inorganic Chemistry, Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen Universitätsstraße 5-7 45117 Essen Germany stephan.schulz@uni-due.de.
Abstract:
Cyclic voltammetry (CV) studies of two L(X)Ga-substituted dipnictenes [L(R2N)GaE]2 (E = Sb, R = Me 1; E = Bi; R = Et 2; L = HC[C(Me)NDipp]2; Dipp = 2,6-i-Pr2C6H3) showed reversible reduction events. Single electron reduction of 1 and 2 with KC8 in DME in the presence of benzo-18-crown-6 (B-18-C-6) gave the corresponding dipnictenyl radical anions (DME)[K(B-18-C-6)][L(R2N)GaE]2 (E = Sb, R = Me 3; E = Bi, R = Et 4). Radical anions 3 and 4 were characterized by EPR, UV-vis and single crystal X-ray diffraction, while quantum chemical calculations gave deeper insight into the nature of the chemical bonding.
More Related Videos
Related Concept Videos
Ionic Bonding and Electron Transfer
Valence Bond Theory
Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
Aromatic Hydrocarbon Cations: Structural Overview
Removing one hydrogen from the intervening CH2 group...
Radicals: Electronic Structure and Geometry
Accordingly, the structure of a trivalent radical lies between the geometries of carbocations and carbanions. An sp2-hybridized carbocation is trigonal planar, while an sp3-hybridized carbanion is trigonal pyramidal. Here, the difference in geometry is...

![The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)