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Updated: Oct 13, 2025

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

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Silacyclization through palladium-catalyzed intermolecular silicon-based C(sp2)-C(sp3) cross-coupling

Ying Qin1, Lianghui Li1, Jin-Yuan Liang1

  • 1State Key Laboratory and Institute of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University Tianjin 300071 China dongbing.chem@nankai.edu.cn.

Chemical Science
|November 11, 2021
PubMed
Summary

This study introduces a novel palladium-catalyzed silicon-based cross-coupling reaction for synthesizing sila-benzo[b]oxepines. This efficient ring expansion strategy offers a new route for creating complex silicon-containing heterocyclic compounds.

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