Related Experiment Video
Updated: Oct 13, 2025

Measurement and Analysis of Atomic Hydrogen and Diatomic Molecular AlO, C2, CN, and TiO Spectra Following Laser-induced Optical Breakdown
Published on: February 14, 2014
Laser spectroscopy of helium solvated molecules: probing the inertial response
1Department of Chemistry, University of Adelaide, SA 5005, Australia.
Abstract:
Helium is the only solvent within which molecules can "freely" rotate, albeit with an increased moment of inertia relative to the gas phase. Evidence for this can be obtained by performing infrared laser spectroscopy on molecules embedded large helium clusters (nanodroplets), which often reveals rotationally resolved lines that are more closely spaced than in vacuo. The additional rotational inertia results from coupling of the helium to the molecule (rotor), and decreases in going from heavy (e.g., SF6) to light (e.g., CH4) rotors due to a partial breakdown in the adiabatic (following) approximation; faster (lighter) rotors cannot couple as well to helium since their effective interaction with helium is less anisotropic. In addition to this "mass" dependence to the coupling, there is also a time dependence to it, which shows up in the IR spectra as an asymmetry in the rovibrational lineshapes; this results from a delay in the response of helium to the change in rotational speed of the solvated molecule (when ΔJ = ±1). In this perspective we discuss the coupling between various probe molecules and helium that have been investigated by infrared laser spectroscopy in the frequency domain.
Related Concept Videos
IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration
According to Hooke's law, the vibrational frequency is directly proportional to...
IR Spectroscopy: Molecular Vibration Overview
Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...
Chemical Shift: Internal References and Solvent Effects
The internal reference compound generally used in NMR spectroscopy is tetramethylsilane (TMS). TMS is preferred because it is chemically inert, soluble in NMR solvents, and easily removable. Also, the highly shielded methyl protons in TMS yield an intense...
Atomic Emission Spectroscopy: Lab
¹H NMR of Labile Protons: Temporal Resolution
The –OH proton in alcohols typically appears in the range of δ 2 to 5 ppm but can vary depending on the specific...
UV–Vis Spectroscopy: Molecular Electronic Transitions

