Improving the Comprehensive Performance of Na_0.7MnO₂ for Sodium Ion Batteries by ZrO₂ Atomic Layer Deposition

Sodium ion batteries with Na-Mn-O compounds as cathodes have been widely studied as substitutes for lithium ion batteries due to their abundant resources. However, the relatively poor cycling stability and low capacity of Na-Mn-O compounds significantly limit their applications. Different approaches, including element substitution and surface modification, have been applied to improve the electrochemical performance of those cathode materials. Herein, element doping and coating of ZrO₂ on Na_0.7MnO₂ particles have been achieved by atomic layer deposition followed by post-annealing. The rate capability and cycling stability of the modified materials were significantly improved, and the mechanism of performance enhancement was revealed. The ZrO₂ coatings acted as a stable interfacial layer to enhance the cycling stability of Na_0.7MnO₂ by suppressing side reactions between the electrode and electrolyte. The doping of transition metal ions reduced energy barriers for sodium ion insertion and deintercalation during charge/discharge cycling, further improving the charge/discharge capacity and rate performance of Na_0.7MnO₂.