Synergetic modulation of surface alkali and oxygen vacancy over SrTiO₃for the CO₂photodissociation

Photochemical conversion of CO₂into solar fuels is one of the promising strategies to reducing the CO₂emission and developing a sustainable carbon economy. For the more efficient utilization of solar spectrum, several approaches were adopted to pursue the visible-light-driven SrTiO₃. Herein, oxygen vacancy was introduced over the commercial SrTiO₃(SrTiO_3-) via the NaBH₄thermal treatment, to extend the light absorption and promote the CO₂adsorption over SrTiO₃. Due to the mid-gap states resulted from the oxygen deficiency, combined with the intrinsic energy level of SrTiO₃, the SrTiO_3-catalyst exhibited excellent CO productivity (4.1 μmolˑg^-1ˑh^-1) and stability from the CO₂photodissociation under the visible-light irradiation (λ > 400 nm). Then, surface alkalization over SrTiO_3-(OH-SrTiO_3-) was carried out to further enhance the CO₂adsorption/activation over the surface base sites and provide the OH ions as hole acceptor, the surface alkali OH connected with Sr site of SrTiO₃could also weaken the Sr-O bonding thus facilitate the regeneration of surface oxygen vacancy under the light illumination, thus resulting in 1.5 times higher CO productivity additionally. This study demonstrates that the synergetic modulation of alkali OH and oxygen vacancy over SrTiO₃could largely promote the CO₂photodissociation activity.