Magnetic modulation of core@shell MoS₂-based flower-like multicomponent nanocomposites to improve microwave...

Nanocomposites with a three-dimensional (3D) flower-like geometrical morphology were considered as excellent microwave absorbers (MAs) because of the numerous effective sites for the multiple reflections of electromagnetic (EM) wave. Herein, for optimizing the EM matching characteristic and taking full advantage of interface polarization, a strategy of magnetic modulation was proposed to further improve the EM wave absorption performances (EMWAPs) of MoS₂-based nanocomposites. We adopted a simple hydrothermal route and a combined method of hydrothermal treatment/hydrogen reduction to synthesize core@shell CoFe₂O₄@MoS₂ and CoFe@MoO₂/MoS₂ flower-like nanocomposites, respectively. The obtained results indicated that the hydrogen reduction effectively improved their magnetic properties and magnetic loss capabilities, and their 3D flower-like geometrical morphologies were well maintained during the hydrogen reduction process. The obtained core@shell CoFe@MoO₂/MoS₂ flower-like nanocomposites presented the extraordinary comprehensive EMWAPs including the optimal reflection loss value of -54.83 dB with the matching thicknesses (d_m) value of 2.05 mm and effective absorption bandwidth value of 6.40 GHz with the d_m value of 2.59 mm, which were evidently superior to the properties of CoFe₂O₄@MoS₂. Therefore, the findings provided an effective pathway to further improve EMWAPs of MoS₂-based core@shell nanocomposites and the as-prepared core@shell CoFe@MoO₂/MoS₂ flower-like nanocomposites could be utilized as the novel high-efficient MAs.