Developing Macro-Raman Mapping as a Tool for Studying the Pigment Distribution of Art Objects

Raman spectroscopy is a well-appreciated technique in cultural heritage research for its ability to obtain molecular information nondestructively. During Raman mapping experiments, advantage is taken of the excellent spatial resolution of the approach, allowing to visualize the spatial distribution of the molecules. In the current research, macro-Raman mapping is proposed, allowing us to map large areas of an artwork (typically tens or hundreds of square centimeters). Therefore, a new setup is made, using a commercially available mobile Raman spectrometer and fast translation stages. Moreover, the probe is equipped with a triangulator to measure the distance to the surface of the artwork and thus achieving accurate focusing of the Raman probe. Finally, the correct setup is guaranteed by using a calibration module that is designed to allow for spectral calibration and aligning all components of the probe. The use of the method is demonstrated by three cases, where different data processing techniques are illustrated.