Facile Modification of NF Membrane by Multi-Layer Deposition of Polyelectrolytes for Enhanced Fouling Resistance

Fouling not only deteriorates the membrane structure but also compromises the quality of the permeate and has deleterious consequences on the membrane operation. In the current study, a commercial thin film composite nanofiltration membrane (NF90) was modified by sequentially depositing oppositely charged polycation (poly(allylamine hydrochloride)) and polyanion (poly(acrylic acid)) polyelectrolytes using the layer-by-layer assembly method. The water contact angle was decreased by ~10° after the coating process, indicating increased hydrophilicity. The surface roughness of the prepared membranes decreased from 380 nm (M-0) to 306 nm (M-10) and 366 nm (M-20). M-10 membrane showed the highest permeate flux of 120 L m^-2 h^-1 with a salt rejection of >98% for MgSO₄ and NaCl. The fabricated membranes M-20 and M-30 showed 15% improvement in fouling resistance and maintained the initial permeate flux longer than the pristine membrane.